With the wide application of large language models (LLMs) in real-world scenarios, the value implication of their outputs is crucial. However, existing evaluation benchmarks suffer from insufficient coverage of value dilemmas in daily scenarios involving multiple value conflicts and simplistic evaluation formalisms that fail to assess LLMs' value alignment.

To address these issues, we propose D2VBench, a value alignment benchmark comprising 10,000 instances of real daily dilemma scenarios constructed through a multi-stage collaboration between LLMs and humans, grounded in 158 manually annotated fine-grained value concepts. For evaluation on the benchmark, we present a hybrid evaluation paradigm that integrates multiple-choice questions with open-ended questions.

We conduct comprehensive evaluations on eight mainstream LLMs. Experimental results demonstrate that D2VBench exhibits high reliability and robustness, effectively reflecting the LLMs' alignment across different value categories and dimensions, and providing a more realistic and fine-grained tool for research on value alignment.

The dataset is available at https://github.com/tjunlp-lab/D2VBench.